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Diazo Compounds: Versatile Synthons for the Synthesis of Nitrogen Heterocycles via Transition Metal‐Catalyzed Cascade C–H Activation/Carbene Insertion/Annulation Reactions
Author(s) -
Xiang Yunyu,
Wang Cong,
Ding Qiuping,
Peng Yiyuan
Publication year - 2019
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201800960
Subject(s) - diazo , chemistry , synthon , annulation , carbene , catalysis , intramolecular force , transition metal , cascade , combinatorial chemistry , nitrogen , cascade reaction , medicinal chemistry , stereochemistry , photochemistry , organic chemistry , chromatography
This review covers some unique diazo compounds, the coupling partners to access various versatile functionalized nitrogen heterocycles, such as indoles, indolines, isoquinolines, isoquinolones, and so on. Different transition metals (such as Rh, Pd, Ru, Ir, Cu, and Co) are involved in these transformations, which involve consecutive processes: transition metal‐catalyzed cascade C–H activation/carbene insertion/intramolecular annulation.