Ruthenium (II)‐Catalyzed Oxidant‐Free Coupling/Cyclization of Benzimidates and Sulfoxonium Ylides to Form Substituted Isoquinolines | Zendy

Shi Xinxia | Zendy; Wang Rongchao | Zendy; Zeng Xiaofei | Zendy; Zhang Yilan | Zendy; Hu Huiling | Zendy; Xie Chunsong | Zendy; Wang Min | Zendy

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Ruthenium (II)‐Catalyzed Oxidant‐Free Coupling/Cyclization of Benzimidates and Sulfoxonium Ylides to Form Substituted Isoquinolines

Author(s) -

Shi Xinxia,

Wang Rongchao,

Zeng Xiaofei,

Zhang Yilan,

Hu Huiling,

Xie Chunsong,

Wang Min

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201800844

Subject(s) - chemistry , isoquinoline , ruthenium , annulation , catalysis , cascade , combinatorial chemistry , surface modification , alkynylation , organic chemistry , chromatography

A ruthenium‐catalyzed direct mono‐C−H functionalization/annulation cascade reaction of benzimidates and sulfoxonium ylides has been developed. The reaction proceeds smoothly with a broad range of substrates, giving access to a variety of isoquinoline derivatives in moderate to good yields using an organic acid additive under oxidant free conditions.

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