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DDQ‐Promoted Allylic C−H Phosphorylation of 1,3‐Diarylpropenes
Author(s) -
Chen Qian,
Wen Chunxiao,
Wang Xiaofeng,
Yu Guodian,
Ou Yingcong,
Huo Yanping,
Zhang Kun
Publication year - 2018
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201800804
Subject(s) - allylic rearrangement , chemistry , phosphorylation , compatibility (geochemistry) , yield (engineering) , functional group , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , chemical engineering , biochemistry , composite material , materials science , polymer , engineering
Abstract An efficient allylic C−H phosphorylation has been achieved through the DDQ‐promoted cross‐dehydrogenative coupling of 1,3‐diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility.