DDQ‐Promoted Allylic C−H Phosphorylation of 1,3‐Diarylpropenes | Zendy

Chen Qian | Zendy; Wen Chunxiao | Zendy; Wang Xiaofeng | Zendy; Yu Guodian | Zendy; Ou Yingcong | Zendy; Huo Yanping | Zendy; Zhang Kun | Zendy

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DDQ‐Promoted Allylic C−H Phosphorylation of 1,3‐Diarylpropenes

Author(s) -

Chen Qian,

Wen Chunxiao,

Wang Xiaofeng,

Yu Guodian,

Ou Yingcong,

Huo Yanping,

Zhang Kun

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201800804

Subject(s) - allylic rearrangement , chemistry , phosphorylation , compatibility (geochemistry) , yield (engineering) , functional group , medicinal chemistry , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , chemical engineering , biochemistry , composite material , materials science , polymer , engineering

An efficient allylic C−H phosphorylation has been achieved through the DDQ‐promoted cross‐dehydrogenative coupling of 1,3‐diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility.

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