Expedient Synthesis of 1,4‐Benzodiazepines via a Tandem Condensation/[1,5]‐Hydride Transfer/Cyclization Process | Zendy

Liu Siyuan | Zendy; Zhao Tuan | Zendy; Qu Jingping | Zendy; Wang Baomin | Zendy

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Expedient Synthesis of 1,4‐Benzodiazepines via a Tandem Condensation/[1,5]‐Hydride Transfer/Cyclization Process

Author(s) -

Liu Siyuan,

Zhao Tuan,

Qu Jingping,

Wang Baomin

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201800781

Subject(s) - chemistry , tandem , benzaldehyde , hydride , condensation , combinatorial chemistry , atom economy , process (computing) , transformation (genetics) , organic chemistry , catalysis , aerospace engineering , programming language , hydrogen , biochemistry , physics , computer science , gene , thermodynamics , engineering

An expedient approach to 1,4‐benzodiazepines via a tandem condensation/[1,5]‐hydride shift/cyclization process has been developed. This transformation started from readily available o ‐amino benzaldehyde and aminomalonate and was promoted by low‐cost FeCl 3 with high step and atom economy.

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