Radical C−H‐Amination of Heteroarenes using Dual Initiation by Visible Light and Iodine | Zendy

Lucchetti Nicola | Zendy; Tkacheva Anastasia | Zendy; Fantasia Serena | Zendy; Muñiz Kilian | Zendy

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Radical C−H‐Amination of Heteroarenes using Dual Initiation by Visible Light and Iodine

Author(s) -

Lucchetti Nicola,

Tkacheva Anastasia,

Fantasia Serena,

Muñiz Kilian

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201800677

Subject(s) - chemistry , amination , iodine , reagent , photochemistry , visible spectrum , combinatorial chemistry , organic chemistry , catalysis , physics , optoelectronics

A novel light‐induced C−H amination of heteroarenes can be accomplished with preformed iodine(III) reagents as the combined oxidant and nitrogen source. The reaction requires the use of a small amount of molecular iodine, which under photochemical activation generates in situ an iodine(I) reagent as the initiator of the radical amination reaction. A total of 32 examples exemplify the broad scope of the transformation.

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