Premium
Rhodium‐Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides
Author(s) -
Arisawa Mieko,
Tazawa Takeru,
Ichinose Wataru,
Kobayashi Haruki,
Yamaguchi Masahiko
Publication year - 2018
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201800630
Subject(s) - chemistry , phosphine , rhodium , aryl , catalysis , medicinal chemistry , organic chemistry , sulfide , flue gas desulfurization , combinatorial chemistry , alkyl
Dialkyl(heteroaryl)phosphine sulfides were synthesized by the rhodium‐catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl)phosphine sulfides containing five‐ and six‐membered heteroaryl groups. Various dialkyl(heteroaryl)phosphines were obtained by desulfurization.