Synthesis of β‐Trifluoromethylated Alkyl Azides  via  a Manganese‐Catalyzed Trifluoromethylazidation of Alkenes with CF 3 SO 2 Na and TMSN 3 | Zendy

Zhang Yuecheng | Zendy; Han Xulin | Zendy; Zhao Jiquan | Zendy; Qian Zijian | Zendy; Li Tianmei | Zendy; Tang Yuqing | Zendy; Zhang HongYu | Zendy

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Synthesis of β‐Trifluoromethylated Alkyl Azides via a Manganese‐Catalyzed Trifluoromethylazidation of Alkenes with CF 3 SO 2 Na and TMSN 3

Author(s) -

Zhang Yuecheng,

Han Xulin,

Zhao Jiquan,

Qian Zijian,

Li Tianmei,

Tang Yuqing,

Zhang HongYu

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201800488

Subject(s) - chemistry , manganese , alkyl , catalysis , organic chemistry , combinatorial chemistry , medicinal chemistry

A convenient and efficient manganese‐catalyzed trifluoromethylazidation of alkenes has been developed by utilizing inexpensive and readily available CF 3 SO 2 Na under mild conditions. The various β‐trifluoromethylated alkyl azides were directly obtained from corresponding allyl, vinyl, chain terminal and internal alkenes, and easily further transformed into other CF 3 ‐containing compounds.

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