Cascade Formation of C 3 ‐Unsymmetric Spirooxindoles via PhI(OAc) 2 ‐Mediated Oxidative C−C/C−N Bond Formation | Zendy

Sun Jiyun | Zendy; Li Guangchen | Zendy; Zhang Guangtao | Zendy; Cong Ying | Zendy; An Xuechan | Zendy; ZhangNegrerie Daisy | Zendy; Du Yunfei | Zendy

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Cascade Formation of C 3 ‐Unsymmetric Spirooxindoles via PhI(OAc) 2 ‐Mediated Oxidative C−C/C−N Bond Formation

Author(s) -

Sun Jiyun,

Li Guangchen,

Zhang Guangtao,

Cong Ying,

An Xuechan,

ZhangNegrerie Daisy,

Du Yunfei

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201800314

Subject(s) - hypervalent molecule , chemistry , oxidative phosphorylation , iodine , cascade , medicinal chemistry , stereochemistry , organic chemistry , biochemistry , chromatography

A series of C 3 ‐unsymmetric spirooxindoles were achieved by reaction of diphenylmalonamides with PhI(OAc) 2 (PIDA) under metal‐free conditions. Control experiments suggest that the hypervalent iodine‐mediated reaction undergoes a cascade process involving an oxidative C−C bond formation preceeding an oxidative C−N bond formation.

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