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Enantioselective Synthesis of trans ‐Vicinal Diamines via Rhodium‐Catalyzed [2+2] Cycloaddition of Allenamides
Author(s) -
Zheng WeiFeng,
Sun GuiJun,
Chen Liang,
Kang Qiang
Publication year - 2018
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201800021
Subject(s) - enantioselective synthesis , chemistry , vicinal , cycloaddition , rhodium , intermolecular force , catalysis , diamine , combinatorial chemistry , organic chemistry , stereochemistry , molecule
An efficient protocol for the enantioselective Rh‐catalyzed intermolecular head‐to‐head [2+2] cycloaddition of allenamides was developed. A variety of enantio‐enriched cyclobutane‐1,2‐diamine derivatives were achieved in good yields with good to excellent enantioselectivities.