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Transition‐Metal‐Free Synthesis of Acridones via Base‐Mediated Intramolecular Oxidative C−H Amination
Author(s) -
Wei WenTao,
Sheng JianFei,
Miao Hui,
Luo Xiang,
Song XianHeng,
Yan Ming,
Zou Yong
Publication year - 2018
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201701579
Subject(s) - chemistry , amination , intramolecular force , transition metal , free base , dimethyl sulfoxide , oxidative phosphorylation , sulfoxide , base (topology) , potassium , combinatorial chemistry , polymer chemistry , organic chemistry , catalysis , salt (chemistry) , mathematical analysis , biochemistry , mathematics
Intramolecular oxidative C−H amination of 2‐aminobenzophenones was achieved in the presence of potassium tert ‐butoxide and dimethyl sulfoxide. A series of functionalized acridones were prepared in moderate to excellent yields in a mild, efficient, and transition‐metal‐free manner.