Premium
Direct Synthesis of Sulfinamides by the Copper‐Catalyzed Electrophilic Amidation of Sulfenate Anions
Author(s) -
Dai Qiang,
Zhang Junliang
Publication year - 2018
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201701510
Subject(s) - chemistry , electrophilic amination , reagent , electrophile , copper , amination , catalysis , combinatorial chemistry , organic chemistry
A method for the construction of sulfinamides via the copper‐catalyzed electrophilic amination of sulfenate anions using N ‐benzoyloxyamines as the amination reagents. This procedure featured with the capture of in‐situ generated sulfenate anions from β ‐sulfinyl esters under mild conditions, which provides an efficient strategy for the synthesis of diverse sulfinamides in moderate to good yields.