Regioselective Silver‐Catalyzed Carbon‐Phosphorus Difunctionalization of Maleimides: One‐Step Construction of Phosphonylated Indolylmaleimides and Pyrrolylmaleimides | Zendy

Yang ZhenHua | Zendy; Tan HongRu | Zendy; Zhu JiaNan | Zendy; Zheng Jian | Zendy; Zhao ShengYin | Zendy

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Regioselective Silver‐Catalyzed Carbon‐Phosphorus Difunctionalization of Maleimides: One‐Step Construction of Phosphonylated Indolylmaleimides and Pyrrolylmaleimides

Author(s) -

Yang ZhenHua,

Tan HongRu,

Zhu JiaNan,

Zheng Jian,

Zhao ShengYin

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201701431

Subject(s) - chemistry , regioselectivity , diphenylphosphine , catalysis , intermolecular force , phosphorus , organic chemistry , diphenylphosphine oxide , carbon fibers , combinatorial chemistry , molecule , phosphine , materials science , composite number , composite material

An efficient silver‐catalyzed intermolecular carbon‐phosphorus difunctionalization of maleimides with indoles/pyrroles and organophosphorus compounds including dialkyl phosphites and diphenylphosphine oxide was developed. A diverse range of phosphonylated indolylmaleimides and pyrrolylmaleimides were obtained in good yields and excellent regioselectivity, involving C−P and C−C bond formations. This methodology is very practical and enables a one‐step construction of difunctionalized maleimides.

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