Palladium‐catalysed  O ‐Allylation of α‐Hydroxyphosphonates: An Expedient Entry into Phosphono‐oxaheterocycles | Zendy

Kerim Mansour Dolé | Zendy; Cattoen Martin | Zendy; Fincias Nicolas | Zendy; Dos Santos Aurélie | Zendy; Arseniyadis Stellios | Zendy; El Kaïm Laurent | Zendy

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Palladium‐catalysed O ‐Allylation of α‐Hydroxyphosphonates: An Expedient Entry into Phosphono‐oxaheterocycles

Author(s) -

Kerim Mansour Dolé,

Cattoen Martin,

Fincias Nicolas,

Dos Santos Aurélie,

Arseniyadis Stellios,

El Kaïm Laurent

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201701150

Subject(s) - chemistry , palladium , ring closing metathesis , metathesis , ring (chemistry) , combinatorial chemistry , catalysis , salt metathesis reaction , stereochemistry , organic chemistry , polymer , polymerization

We report here an unprecedented palladium‐catalysed O ‐allylation of α‐hydroxyphosphonates. The method was eventually included in a sequential Pudovik/Tsuji‐Trost type O ‐allylation/Ring‐Closing Metathesis to afford a variety of phosphorylated heterocycles of various sizes ranging from 5 to 16 starting from readily available aldehydes.

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