Visible‐Light‐Promoted Alkylation of Indoles with Tertiary Amines by the Oxidation of a  sp  3  C‐H Bond | Zendy

Ding Xuan | Zendy; Dong ChunLin | Zendy; Guan Zhi | Zendy; He YanHong | Zendy

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Visible‐Light‐Promoted Alkylation of Indoles with Tertiary Amines by the Oxidation of a sp 3 C‐H Bond

Author(s) -

Ding Xuan,

Dong ChunLin,

Guan Zhi,

He YanHong

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201701131

Subject(s) - chemistry , rose bengal , indole test , alkylation , photosensitizer , photochemistry , visible spectrum , medicinal chemistry , catalysis , organic chemistry , physics , optoelectronics

A visible‐light driven reaction for the synthesis of 3‐arylmethyl indole derivatives using tertiary amines and indoles was first reported. Corresponding products were obtained with yields of up to 70%, and various functional groups on the indoles were well tolerated when Rose Bengal was used as a photosensitizer and air was used as a green oxidant under mild reaction conditions.

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