Reactivity and Synthetic Applications of α‐Functionalized Oxime Acetates: Divergent Access to Fulleropyrrolidines and Mono‐ and Disubstituted 1‐Fulleropyrrolines  via  Copper‐Catalyzed Redox‐Neutral N‐Heteroannulation with [60]Fullerene | Zendy

Liu TongXin | Zendy; Hua Shaoshuai | Zendy; Ma Nana | Zendy; Zhang Pengling | Zendy; Bi Jingjing | Zendy; Zhang Zhiguo | Zendy; Zhang Guisheng | Zendy

Premium

Reactivity and Synthetic Applications of α‐Functionalized Oxime Acetates: Divergent Access to Fulleropyrrolidines and Mono‐ and Disubstituted 1‐Fulleropyrrolines via Copper‐Catalyzed Redox‐Neutral N‐Heteroannulation with [60]Fullerene

Author(s) -

Liu TongXin,

Hua Shaoshuai,

Ma Nana,

Zhang Pengling,

Bi Jingjing,

Zhang Zhiguo,

Zhang Guisheng

Publication year - 2018

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201701091

Subject(s) - chemistry , chemoselectivity , reactivity (psychology) , oxime , redox , catalysis , fullerene , combinatorial chemistry , copper , substrate (aquarium) , medicinal chemistry , organic chemistry , medicine , oceanography , alternative medicine , pathology , geology

The unique reactivity and synthetic applications of oxime acetate derivatives with N, O and S substituents at the α‐position are disclosed for the first time, which leads to 2‐substituted fulleropyrrolidines and mono‐ and disubstituted 1‐fulleropyrrolines via copper‐catalyzed redox‐neutral N‐heteroannulation reactions with C 60 . This transformation is operationally simple and has a broad substrate scope and good functional group tolerance. Theoretical calculations at the level of B3LYP/6‐31G(d) were performed to elucidate the chemoselectivity of the reaction.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research