Synthesis of Dihydrophosphaisocoumarins through a Palladium‐Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with 1,3‐Dienes | Zendy

Son JeongYu | Zendy; Kim Hyunseok | Zendy; Jeon Woo Hyung | Zendy; Baek Yonghyeon | Zendy; Seo Boram | Zendy; Um Kyusik | Zendy; Lee Kooyeon | Zendy; Lee Phil Ho | Zendy

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Synthesis of Dihydrophosphaisocoumarins through a Palladium‐Catalyzed Oxidative Cyclization of Arylphosphonic Acid Monoethyl Esters with 1,3‐Dienes

Author(s) -

Son JeongYu,

Kim Hyunseok,

Jeon Woo Hyung,

Baek Yonghyeon,

Seo Boram,

Um Kyusik,

Lee Kooyeon,

Lee Phil Ho

Publication year - 2017

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201700742

Subject(s) - chemistry , palladium , catalysis , oxidative phosphorylation , alkyl , aryl , organic chemistry , combinatorial chemistry , biochemistry

An efficient synthetic method for the selective preparation of dihydrophosphaisocoumarins and their derivatives was developed through a palladium‐catalyzed oxidative cyclization reaction of a wide range of arylphosphonic acid monoethyl esters with activated and unactivated 1,3‐dienes, including 1‐aryl‐substituted 1,3‐dienes and 1‐alkyl‐substituted 1,3‐dienes, thus opening a new avenue for the synthesis of phosphaheterocyclic compounds.

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