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Selective C( sp 3 )–H Monoarylation Catalyzed by a Covalently Cross‐Linked Reverse Micelle‐Supported Palladium Catalyst
Author(s) -
Hoyt Caroline B.,
Lee LiChen,
He Jian,
Yu JinQuan,
Jones Christopher W.
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201700707
Subject(s) - chemistry , micelle , palladium , catalysis , ligand (biochemistry) , selectivity , homogeneous , covalent bond , homogeneous catalysis , steric effects , combinatorial chemistry , photochemistry , organic chemistry , aqueous solution , biochemistry , physics , receptor , thermodynamics
In this work, we illustrate the performance of a solvated micelle‐supported ligand as a platform for coordination with palladium for C–H arylation. The micelle‐supported ligand is one of the first applications of a micelle‐supported ligand for C–H arylation, and provides a tunable support for future elaboration. The use of a spatially constrained system promoted selectivity trends influenced by both the sterics and electronics of the system, differing from the homogeneous catalyst, with high yields and selectivities.