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Interaction of gem ‐Difluorinated Iodides with Silyl Enol Ethers Mediated by Photoredox Catalysis
Author(s) -
Chernov Grigory N.,
Levin Vitalij V.,
Kokorekin Vladimir A.,
Struchkova Marina I.,
Dilman Alexander D.
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201700423
Subject(s) - chemistry , enol , silylation , iridium , catalysis , photochemistry , silyl enol ether , photoredox catalysis , coupling reaction , photocatalysis , organic chemistry , combinatorial chemistry
A method for the synthesis of β,β‐difluorinated ketones by coupling of α,α‐difluorinated iodides with silyl enol ethers is described. The reaction is performed in the presence of iridium(III) photocatalysts under the irradiation with 400 nm light emitting diodes.