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Palladium/Phosphorus‐Doped Porous Organic Polymer as Recyclable Chemoselective and Efficient Hydrogenation Catalyst under Ambient Conditions
Author(s) -
Ding ZongCang,
Li CunYao,
Chen JunJia,
Zeng JiaHao,
Tang HaiTao,
Ding YunJie,
Zhan ZhuangPing
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201700374
Subject(s) - palladium , chemistry , catalysis , polymer , heck reaction , porosity , ligand (biochemistry) , doping , phosphorus , heterogeneous catalysis , organic chemistry , nanoparticle , hydrogen , inorganic chemistry , polymer chemistry , chemical engineering , materials science , biochemistry , receptor , optoelectronics , engineering
A new type of phosphorus‐doped porous organic polymer (POP) has been readily synthesized through a Heck reaction, which could be used not only as a support but also a ligand for palladium nanoparticles. The dual‐functional material supported palladium nanocatalyst was used for the efficient and chemoselective hydrogenation of varieties of nitroarenes and α,β‐unsaturated compounds, as well as for the synthesis of indoles from 2‐nitrophenylacetonitrile under 1 atm hydrogen in green solvents at room temperature. No obvious aggregation and loss of catalytic activity of the new nanocatalyst were observed after 10 runs in the reaction.