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Palladium‐Catalyzed Regioselective Allylation of Chloromethyl(hetero)arenes with Allyl Pinacolborate
Author(s) -
Zhang Sheng,
Ullah Aziz,
Yamamoto Yoshinori,
Bao Ming
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201700350
Subject(s) - regioselectivity , chemistry , palladium , catalysis , organic chemistry
The palladium‐catalyzed regioselective allylation reaction between chloromethyl(hetero)arenes and allyl pinacolborate is reported in this work. Chloromethylarenes smoothly reacted with allyl pinacolborate, producing para ‐allylated dearomatization products or para ‐allylated arenes in satisfactory to good yields. 2‐(Chloromethyl)thiophenes and 2‐(chloromethyl)furans bearing substituents on the 5‐positions also smoothly reacted with allyl pinacolborate, producing the 5‐allylated dearomatization products in satisfactory yields.