Intramolecular C−H Alkenylation of  N ‐Alkynylindoles:  Exo  and  Endo  Selective Cyclization According to the Choice of Metal Catalyst | Zendy

Shibata Takanori | Zendy; Baba Takumi | Zendy; Takano Hideaki | Zendy; Kanyiva Kyalo Stephen | Zendy

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Intramolecular C−H Alkenylation of N ‐Alkynylindoles: Exo and Endo Selective Cyclization According to the Choice of Metal Catalyst

Author(s) -

Shibata Takanori,

Baba Takumi,

Takano Hideaki,

Kanyiva Kyalo Stephen

Publication year - 2017

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201700107

Subject(s) - chemistry , intramolecular force , iridium , rhodium , catalysis , dig , medicinal chemistry , metal , stereochemistry , cleavage (geology) , bond cleavage , organic chemistry , computer security , geotechnical engineering , fracture (geology) , computer science , engineering

The intramolecular reaction of 3‐acetyl‐ N ‐alkynylindoles proceeded via C−H bond cleavage at the C2 position. Iridium and rhodium catalysts selectively promoted 6‐ exo ‐dig and 7‐ endo ‐dig cyclization, respectively, and N ‐fused tricyclic compounds were obtained.

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