Formation of Phenyliodonio‐Substituted Spirofurooxindole Trifluoroacetates from  N ‐Substituted 3‐Oxopentanediamides  via  Phenyliodine Bis(trifluoroacetate)‐Mediated Oxidative Cascade Reactions | Zendy

Hu Bei | Zendy; Cao Yang | Zendy; Zhang Bobo | Zendy; ZhangNegrerie Daisy | Zendy; Du Yunfei | Zendy

Premium

Formation of Phenyliodonio‐Substituted Spirofurooxindole Trifluoroacetates from N ‐Substituted 3‐Oxopentanediamides via Phenyliodine Bis(trifluoroacetate)‐Mediated Oxidative Cascade Reactions

Author(s) -

Hu Bei,

Cao Yang,

Zhang Bobo,

ZhangNegrerie Daisy,

Du Yunfei

Publication year - 2017

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201700075

Subject(s) - chemistry , oxidative phosphorylation , halogenation , cascade , oxidative addition , medicinal chemistry , cascade reaction , organic chemistry , catalysis , biochemistry , chromatography

The reaction of N ‐substituted 3‐oxopentanediamides with phenyliodine bis(trifluoroacetate) (PIFA) was found to give a novel class of phenyliodonio‐substituted spirofurooxindole trifluoroacetates under metal‐free conditions. The reaction is postulated to proceed via a cascade process involving an oxidative C—O bond formation, an oxidative C—C bond formation and a final iodination step.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research