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(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation
Author(s) -
Liu XuGe,
Li Qingjiang,
Wang Honggen
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201700066
Subject(s) - chemistry , cobalt , catalysis , substrate (aquarium) , functional group , redox , combinatorial chemistry , scope (computer science) , photochemistry , medicinal chemistry , stereochemistry , organic chemistry , oceanography , computer science , programming language , geology , polymer
Abstract The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)‐catalyzed C(sp 2 )‐H activation and coupling with AgSCF 3 under the assistance of a directing group. The reaction features redox‐neutrality, mild conditions, broad substrate scope, and good functional group tolerance. Preliminary mechanistic studies have been conducted.