(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation | Zendy

Liu XuGe | Zendy; Li Qingjiang | Zendy; Wang Honggen | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation

Author(s) -

Liu XuGe,

Li Qingjiang,

Wang Honggen

Publication year - 2017

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201700066

Subject(s) - chemistry , cobalt , catalysis , substrate (aquarium) , functional group , redox , combinatorial chemistry , scope (computer science) , photochemistry , medicinal chemistry , stereochemistry , organic chemistry , oceanography , computer science , programming language , geology , polymer

The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)‐catalyzed C(sp 2 )‐H activation and coupling with AgSCF 3 under the assistance of a directing group. The reaction features redox‐neutrality, mild conditions, broad substrate scope, and good functional group tolerance. Preliminary mechanistic studies have been conducted.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research