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Preparation of Electrophilic Trifluromethylthio Reagents from Nucleophilic Tetramethylammonium Trifluoromethylthiolate
Author(s) -
Kovács Szabolcs,
Bayarmagnai Bilguun,
Goossen Lukas J.
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201601298
Subject(s) - chemistry , electrophile , tetramethylammonium , nucleophile , reagent , combinatorial chemistry , stoichiometry , organic chemistry , catalysis , ion
A straightforward synthetic entry to the principal classes of electrophilic trifluoromethylthiolating agents is presented. It draws on inexpensive, shelf‐stable tetramethylammonium trifluoromethylthiolate (Me 4 N–SCF 3 ) as the SCF 3 source in the place of stoichiometric coinage metal‐SCF 3 complexes.