Synthesis of Functionalized Hydrazines: Facile Homogeneous (N‐Heterocyclic Carbene)‐Palladium(0)‐Catalyzed Diboration and Silaboration of Azobenzenes | Zendy

Ansell Melvyn B. | Zendy; Kostakis George E. | Zendy; Braunschweig Holger | Zendy; Navarro Oscar | Zendy; Spencer John | Zendy

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Synthesis of Functionalized Hydrazines: Facile Homogeneous (N‐Heterocyclic Carbene)‐Palladium(0)‐Catalyzed Diboration and Silaboration of Azobenzenes

Author(s) -

Ansell Melvyn B.,

Kostakis George E.,

Braunschweig Holger,

Navarro Oscar,

Spencer John

Publication year - 2016

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201601106

Subject(s) - chemistry , diphenylacetylene , palladium , carbene , catalysis , combinatorial chemistry , homogeneous , organic chemistry , polymer chemistry , photochemistry , physics , thermodynamics

The bis(N‐heterocyclic carbene)(diphenylacetylene)palladium complex [Pd(ITMe) 2 (PhC≡CPh)] (ITMe=1,3,4,5‐tetramethylimidazol‐2‐ylidene) acts as a highly active pre‐catalyst in the diboration and silaboration of azobenzenes to synthesize a series of novel functionalized hydrazines. The reactions proceed using commercially available diboranes and silaboranes under mild reaction conditions.

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