Premium
Transition Metal‐Catalyzed Reactions Involving Oximes
Author(s) -
Li Jun,
Hu Yitian,
Zhang Daopeng,
Liu Qing,
Dong Yunhui,
Liu Hui
Publication year - 2017
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600807
Subject(s) - chemistry , oxime , catalysis , cleavage (geology) , organic synthesis , transition metal , bond cleavage , combinatorial chemistry , scope (computer science) , organic chemistry , geotechnical engineering , fracture (geology) , engineering , computer science , programming language
Oximes are an easily prepared and transformed unit, which are widely used in organic synthesis. The oximes, including oxime ethers and esters, could realize various transformations, such as C–H bond activation, Heck‐type reactions, N–O bond cleavage/C–N bond formation, O–H bond cleavage and couplings. However, there is no a comprehensive review on this subject. Herein, we summarize the recent advances over the past 15 years in transition metal‐catalyzed reactions involving oximes, focusing on the reaction scope, limitations and mechanisms.