Directing Group‐Assisted Copper(II)‐Catalyzed  ortho ‐Carbonylation to Benzamide using 2,2′‐Azobisisobutyronitrile (AIBN) | Zendy

Khan Bhuttu | Zendy; Khan Afsar Ali | Zendy; Kant Ruchir | Zendy; Koley Dipankar | Zendy

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Directing Group‐Assisted Copper(II)‐Catalyzed ortho ‐Carbonylation to Benzamide using 2,2′‐Azobisisobutyronitrile (AIBN)

Author(s) -

Khan Bhuttu,

Khan Afsar Ali,

Kant Ruchir,

Koley Dipankar

Publication year - 2016

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201600664

Subject(s) - chemistry , benzothiophene , cyanation , benzofuran , azobisisobutyronitrile , regioselectivity , carbonylation , furan , pyrrole , thiophene , catalysis , organic chemistry , combinatorial chemistry , medicinal chemistry , polymerization , polymer , carbon monoxide

An efficient copper‐catalyzed regioselective C—H bond carbonylation of benzamides has been developed using 2,2′‐azobisisobutyronitrile (AIBN) as traceless cyanating agent. The non‐toxic and readily available AIBN was used for the carbonylative cyclization of benzamides via copper catalysis. The method is also applicable for the regioselective cyanation of furan, benzofuran, thiophene, benzothiophene, and pyrrole carboxamide derivatives.

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