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Synthesis and Properties of Hydrazino Amino Acyclic Carbenes of Gold(I), Platinum(II), Palladium(II) and Rhodium(III)
Author(s) -
Tšupova Svetlana,
Rudolph Matthias,
Rominger Frank,
Hashmi A. Stephen K.
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600615
Subject(s) - rhodium , chemistry , palladium , cycloisomerization , platinum , carbene , nucleophile , hydrazine (antidepressant) , catalysis , medicinal chemistry , stereochemistry , organic chemistry , chromatography
The nucleophilic addition of protected and substituted hydrazine derivatives to isonitrile complexes of gold(I), platinum(II), palladium(II) and rhodium(III) provides the corresponding hydrazino amino acyclic carbene complexes. These are characterized by their spectroscopic data, four different X‐ray single crystal structure analyses and their catalytic activity in the gold(I)‐catalyzed cycloisomerization of N ‐propargylcarboxamides to alkylideneoxazolines is investigated.