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Nickel‐ or Iron‐Catalyzed Cross‐Coupling of Aryl Carbamates with Arylsilanes
Author(s) -
Shi WenJuan,
Zhao HongWei,
Wang Yang,
Cao ZhiChao,
Zhang LiSheng,
Yu DaGang,
Shi ZhangJie
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600590
Subject(s) - chemistry , aryl , electrophile , catalysis , steric effects , nickel , coupling reaction , coupling (piping) , combinatorial chemistry , organic chemistry , alkyl , metallurgy , materials science
Aryl carbamates were for the first time applied as electrophiles in the cross‐coupling with arylsilanes via nickel or iron catalysis to construct valuable biaryl compounds. This new coupling reaction features a good group tolerance and non‐sensitivity to steric hindrance on both aryl carbamates and arylsilanes.