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Palladium‐Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source
Author(s) -
Wang Zechao,
Li Yahui,
Zhu Fengxiang,
Wu XiaoFeng
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600395
Subject(s) - chemistry , palladium , carbonylation , catalysis , carbon monoxide , regioselectivity , molybdenum , functional group , organic chemistry , monoxide , photochemistry , polymer
With molybdenum hexacarbonyl as the carbon monoxide source, a general palladium‐catalyzed carbonylative transformation of the C−H bond on aromatic rings to produce esters has been developed. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. A variety of aliphatic alcohols are suitable reactants here.