Palladium‐Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source | Zendy

Wang Zechao | Zendy; Li Yahui | Zendy; Zhu Fengxiang | Zendy; Wu XiaoFeng | Zendy

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Palladium‐Catalyzed Oxidative Carbonylation of Aromatic C−H Bonds with Alcohols using Molybdenum Hexacarbonyl as the Carbon Monoxide Source

Author(s) -

Wang Zechao,

Li Yahui,

Zhu Fengxiang,

Wu XiaoFeng

Publication year - 2016

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201600395

Subject(s) - chemistry , palladium , carbonylation , catalysis , carbon monoxide , regioselectivity , molybdenum , functional group , organic chemistry , monoxide , photochemistry , polymer

With molybdenum hexacarbonyl as the carbon monoxide source, a general palladium‐catalyzed carbonylative transformation of the C−H bond on aromatic rings to produce esters has been developed. Good yields of the corresponding products have been obtained with wide functional group tolerance and excellent regioselectivity. A variety of aliphatic alcohols are suitable reactants here.

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