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Iodothiocyanation/Nitration of Allenes with Potassium Thiocyanate/Silver Nitrite and Iodine
Author(s) -
Yang Xiaodong,
She Yue,
Chong Ya,
Zhai Huichun,
Zhu He,
Chen Baohua,
Huang Guosheng,
Yan Rulong
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600304
Subject(s) - chemistry , nitration , iodine , thiocyanate , potassium thiocyanate , nitrite , inorganic chemistry , potassium , organic chemistry , nitrate
Direct strategies for the iodothiocyanation and iodonitration of allenes have been developed. In this process, potassium thiocyanate/silver nitrite and molecular iodine are used as the source of SCN, ONO 2 and iodine to provide the desired products in moderate to good yields with high stereoselectivity.