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Cobalt‐Catalyzed Direct Amination of Arenes with Alkylamines via Bidentate‐Chelation Assistance
Author(s) -
Yan Qiangqiang,
Xiao Tangxin,
Liu Zhanxiang,
Zhang Yuhong
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600282
Subject(s) - chemistry , cobalt , amination , catalysis , denticity , chelation , reagent , surface modification , combinatorial chemistry , organic chemistry , medicinal chemistry , crystal structure
Cobalt‐catalyzed C−H amination of arenes with alkylamines by the assistance of 8‐aminoquinoline as auxiliary through sp 2 C−H bond functionalization has been achieved. Attractive features of this protocol include the low loading of the cobalt catalyst and the readily available reagents.