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Metal‐Free Autoxidative Nitrooxylation of Alkenyl Oximes with Molecular Oxygen
Author(s) -
Zhang XiaoWei,
Xiao ZuFeng,
Zhuang YanJun,
Wang MeiMei,
Kang YanBiao
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600147
Subject(s) - chemistry , oxidizing agent , reagent , molecular oxygen , oxygen , metal , nitrite , oxygen atom , organic chemistry , combinatorial chemistry , inorganic chemistry , molecule , nitrate
A metal‐free aerobic autoxidative nitrooxylation of alkenyl oximes mediated by tert ‐butyl nitrite is described. Molecular oxygen is used as the oxidizing reagent, avoiding use of organic trapping reagents such as 2,2,6,6‐tetramethylpiperidine 1‐oxyl (TEMPO). The desired products were obtained in generally high yields.