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Copper‐Mediated 1,2‐Difunctionalization of Styrenes with Sodium Arylsulfinates and tert ‐Butyl Nitrite: Facile Access to α‐Sulfonylethanone Oximes
Author(s) -
Yang Ji,
Liu YanYun,
Song RenJie,
Peng ZhiHong,
Li JinHeng
Publication year - 2016
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201600109
Subject(s) - chemistry , sodium nitrite , intermolecular force , copper , nitrite , sodium , medicinal chemistry , combinatorial chemistry , organic chemistry , molecule , nitrate
A new copper‐mediated synthesis of α‐sulfonylethanone oximes from styrenes, sodium arylsulfinates and tert ‐butyl nitrite ( t‐ BuONO; TBN) is presented. This intermolecular three‐component method enables the one‐step formation of CN and CS bonds under mild conditions, and represents a new, straightforward approach to α‐sulfonylethanone oximes.