Copper‐Mediated 1,2‐Difunctionalization of Styrenes with Sodium Arylsulfinates and  tert ‐Butyl Nitrite: Facile Access to α‐Sulfonylethanone Oximes | Zendy

Yang Ji | Zendy; Liu YanYun | Zendy; Song RenJie | Zendy; Peng ZhiHong | Zendy; Li JinHeng | Zendy

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Copper‐Mediated 1,2‐Difunctionalization of Styrenes with Sodium Arylsulfinates and tert ‐Butyl Nitrite: Facile Access to α‐Sulfonylethanone Oximes

Author(s) -

Yang Ji,

Liu YanYun,

Song RenJie,

Peng ZhiHong,

Li JinHeng

Publication year - 2016

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201600109

Subject(s) - chemistry , sodium nitrite , intermolecular force , copper , nitrite , sodium , medicinal chemistry , combinatorial chemistry , organic chemistry , molecule , nitrate

A new copper‐mediated synthesis of α‐sulfonylethanone oximes from styrenes, sodium arylsulfinates and tert ‐butyl nitrite ( t‐ BuONO; TBN) is presented. This intermolecular three‐component method enables the one‐step formation of CN and CS bonds under mild conditions, and represents a new, straightforward approach to α‐sulfonylethanone oximes.

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