Flow Metal‐Free ArC Bond Formation  via  Photogenerated Phenyl Cations | Zendy

Bergami Matteo | Zendy; Protti Stefano | Zendy; Ravelli Davide | Zendy; Fagi Maurizio | Zendy

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Flow Metal‐Free ArC Bond Formation via Photogenerated Phenyl Cations

Author(s) -

Bergami Matteo,

Protti Stefano,

Ravelli Davide,

Fagi Maurizio

Publication year - 2016

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201600019

Subject(s) - chemistry , aryl , photochemistry , metal , irradiation , flow (mathematics) , flow chemistry , combinatorial chemistry , organic chemistry , catalysis , alkyl , physics , geometry , mathematics , nuclear physics

A convenient photochemical flow protocol for the formation of aryl‐carbon bonds via photogenerated phenyl cations has been developed. A wide range of phenylated products, including biaryls, allylarenes, 2‐arylacetals and benzyl γ‐lactones, was smoothly synthesized in satisfactory yields under metal‐free conditions. The adoption of a flow reactor often allowed us to adopt higher concentrations of substrates and shorter irradiation times compared to those usually employed in batch systems.

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