Metal‐Free Oxidative Decarbonylative Hydroalkylation of Alkynes with Secondary and Tertiary Alkyl Aldehydes | Zendy

Ouyang XuanHui | Zendy; Song RenJie | Zendy; Liu Bang | Zendy; Li JinHeng | Zendy

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Metal‐Free Oxidative Decarbonylative Hydroalkylation of Alkynes with Secondary and Tertiary Alkyl Aldehydes

Author(s) -

Ouyang XuanHui,

Song RenJie,

Liu Bang,

Li JinHeng

Publication year - 2016

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201501113

Subject(s) - chemistry , decarbonylation , alkyl , protonation , peroxide , organic chemistry , medicinal chemistry , catalysis , ion

A new, metal‐free, radical‐mediated oxidative decarbonylative hydroalkylation of various alkynes with secondary and tertiary alkyl aldehydes using di‐ tert ‐butyl peroxide (DTBP) as oxidant is presented. This method enables the simultaneous formation of a CC bond and a CH bond through a sequence of decarbonylation, radical addition and protonation, and provides a straightforward route for transforming alkynes into alkenes with high compatibility with both alkynes and alkyl aldehydes.

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