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Palladium‐Catalyzed Olefination and Arylation of Polyfluoroarenes Using Molecular Oxygen as the Sole Oxidant
Author(s) -
Huang Qiufeng,
Zhang Xinyu,
Qiu Lin,
Wu Jiajun,
Xiao Hanbing,
Zhang Xiaofeng,
Lin Shen
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201500632
Subject(s) - chemistry , molecular oxygen , palladium , catalysis , combinatorial chemistry , oxygen , organic chemistry , atmospheric pressure , oceanography , geology
The palladium‐catalyzed cross‐dehydrogenative‐coupling of polyfluoroarenes with alkenes or simple arenes has been developed. The approach is characterized by using atmospheric pressure of molecular oxygen as the sole oxidant, and provides a straightforward and environmentally benign route to functionalized polyfluoroarenes.