Homogeneous Gold‐Catalyzed Cyclization Reactions of Alkynes with  N ‐ and  S ‐Nucleophiles | Zendy

Debrouwer Wouter | Zendy; Heugebaert Thomas S. A. | Zendy; Roman Bart I. | Zendy; Stevens Christian V. | Zendy

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Homogeneous Gold‐Catalyzed Cyclization Reactions of Alkynes with N ‐ and S ‐Nucleophiles

Author(s) -

Debrouwer Wouter,

Heugebaert Thomas S. A.,

Roman Bart I.,

Stevens Christian V.

Publication year - 2015

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201500520

Subject(s) - nucleophile , chemistry , homogeneous , catalysis , intramolecular force , homogeneous catalysis , combinatorial chemistry , medicinal chemistry , organic chemistry , physics , thermodynamics

This review covers the formation of N ‐ and S ‐containing heterocycles, initiated by gold‐catalyzed nucleophilic attack of N ‐ or S ‐nucleophiles onto alkynes. These types of nucleophiles have been somewhat overlooked as compared to their C ‐ or O ‐counterparts in other reviews. In this particular work, their intramolecular gold‐mediated attack onto alkynes is reviewed in depth. It is structured in such a fashion that the reader will get a clear view of which substrates react in which cyclization mode.

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