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Catalytic Aerobic Oxidation of Arylhydrazides with Iron Phthalocyanine
Author(s) -
Hashimoto Takuma,
Hirose Daisuke,
Taniguchi Tsuyoshi
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201500459
Subject(s) - chemistry , phthalocyanine , catalysis , kinetics , oxidative phosphorylation , reaction mechanism , photochemistry , mechanism (biology) , redox , combinatorial chemistry , oxidation reduction , organic chemistry , biochemistry , physics , philosophy , epistemology , quantum mechanics
A convenient method for the synthesis of 2‐arylazocarboxylates from 2‐arylhydrazinecarboxylates by aerobic oxidation with iron phthalocyanine is described. The reaction is applicable to oxidative activation of 1‐acyl‐2‐phenylhydrazines. Some preliminary experiments suggest Michaelis–Menten kinetics and participation of radical species in the reaction mechanism.