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Copper(I)‐Catalyzed Desulfinative Carboxylation of Sodium Sulfinates using Carbon Dioxide
Author(s) -
Sun Song,
Yu JinTao,
Jiang Yan,
Cheng Jiang
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201500101
Subject(s) - carboxylation , chemistry , carbon dioxide , catalysis , copper , aryl , sodium , inorganic chemistry , functional group , organic chemistry , alkyl , polymer
A copper(I)‐catalyzed desulfinative carboxylation of sodium sulfinates using carbon dioxide has been developed. This reaction showed wide functional group tolerance. A series of sodium aryl‐ and alkenylsulfinates could be converted into the corresponding carboxylic acids in good to excellent yields. Additionally, the reaction mechanism was studied by in situ NMR analysis and isotopic labeling experiments.