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A Polymer‐Bound Monodentate‐P‐Ligated Palladium Complex as a Recyclable Catalyst for the Suzuki–Miyaura Coupling Reaction of Aryl Chlorides
Author(s) -
Zhou YunBing,
Li CunYao,
Lin Min,
Ding YunJie,
Zhan ZhuangPing
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201500070
Subject(s) - chemistry , denticity , palladium , phosphine , aryl , catalysis , suzuki reaction , reactivity (psychology) , polymer chemistry , coupling reaction , polymer , organic chemistry , combinatorial chemistry , medicinal chemistry , crystal structure , alkyl , medicine , alternative medicine , pathology
A three‐fold cross‐linked polymer‐bound phosphine (POL‐Ph 3 P) with high phosphorus content has been prepared. The phosphorus‐containing polymer forms a monodentate‐P‐ligated palladium complex, which shows excellent activity in Suzuki–Miyaura cross‐coupling reactions of aryl chlorides. Importantly, the catalyst Pd/POL‐Ph 3 P is highly stable and can be reused for at least 10 times without losing reactivity.