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2 H ‐Chromenes Generated by an Iron(III) Complex‐Catalyzed Allylic Cyclization
Author(s) -
Calmus L.,
Corbu A.,
Cossy J.
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201500058
Subject(s) - chemistry , allylic rearrangement , catalysis , phenols , natural product , combinatorial chemistry , medicinal chemistry , organic chemistry , stereochemistry
A straightforward method based on an iron(III) complex‐catalyzed cyclization of 2‐(1‐hydroxyallyl)phenols is reported to access a large variety of 2 H ‐chromenes. This method was applied to the total synthesis of a natural product, tephrowatsin B.