Two Consecutive Palladium(II)‐Promoted CH Alkenylation Reactions for the Synthesis of 3‐Alkenylquinolones | Zendy

OrtizdeElguea Verónica | Zendy; Sotomayor Nuria | Zendy; Lete Esther | Zendy

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Two Consecutive Palladium(II)‐Promoted CH Alkenylation Reactions for the Synthesis of 3‐Alkenylquinolones

Author(s) -

OrtizdeElguea Verónica,

Sotomayor Nuria,

Lete Esther

Publication year - 2015

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400931

Subject(s) - chemistry , intramolecular force , palladium , intermolecular force , catalysis , medicinal chemistry , combinatorial chemistry , atom (system on chip) , stereochemistry , organic chemistry , molecule , computer science , embedded system

Highly substituted quinolones are obtained through an efficient and atom economical procedure that involves two consecutive palladium(II)‐catalyzed CH alkenylation reactions. A selective 6‐ endo intramolecular CH alkenylation leads to 4‐substituted quinolones that have been further functionalized at C‐3 through a second intermolecular CH alkenylation reaction.

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