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Acid‐Catalyzed Synthesis of α,β‐Disubstituted Conjugated Enones by a Meyer–Schuster‐Type Rearrangement in Allenols
Author(s) -
Alcaide Benito,
Almendros Pedro,
Cembellín Sara,
Martínez del Campo Teresa
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400928
Subject(s) - chemistry , conjugated system , catalysis , context (archaeology) , combinatorial chemistry , organic chemistry , paleontology , biology , polymer
A novel, direct and simple methodology to gain access to α,β‐disubstituted conjugated enones from α‐allenols in a sustainable metal catalysis context, considering the inexpensiveness and environmentally friendliness of iron(III) species and protons, has been developed.