Gas–Liquid Segmented Flow Microfluidics for Screening Copper/TEMPO‐Catalyzed Aerobic Oxidation of Primary Alcohols | Zendy

Vanoye Laurent | Zendy; Pablos Mertxe | Zendy; de Bellefon Claude | Zendy; FavreRéguillon Alain | Zendy

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Gas–Liquid Segmented Flow Microfluidics for Screening Copper/TEMPO‐Catalyzed Aerobic Oxidation of Primary Alcohols

Author(s) -

Vanoye Laurent,

Pablos Mertxe,

de Bellefon Claude,

FavreRéguillon Alain

Publication year - 2015

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400925

Subject(s) - chemistry , copper , microreactor , alcohol oxidation , catalysis , primary (astronomy) , alcohol , limiting , redox , microfluidics , mass transfer , combinatorial chemistry , organic chemistry , nanotechnology , chromatography , materials science , astronomy , mechanical engineering , physics , engineering

Aerobic oxidation using a combination of copper salts and 2,2,6,6‐tetramethylpiperidine N ‐oxyl (TEMPO) represent useful tools for organic synthesis and several closely related catalyst systems have been reported. To gain further insights, these catalytic systems were evaluated in a gas–liquid segmented flow device. The improvement of oxygen mass transfer has a significant influence on the turnover‐limiting step. Hence, an improved catalytic system using copper(II) as copper source was implemented in a microreactor for the safe and efficient oxidation of primary alcohol.

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