Ruthenium(II)‐Catalyzed Hydrogen Transfer/Annulation Cascade Processes between Alcohols and 2‐Nitrobenzaldehydes | Zendy

Li HuiJing | Zendy; Wang ChenChao | Zendy; Zhu Shuai | Zendy; Dai ChunYang | Zendy; Wu YanChao | Zendy

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Ruthenium(II)‐Catalyzed Hydrogen Transfer/Annulation Cascade Processes between Alcohols and 2‐Nitrobenzaldehydes

Author(s) -

Li HuiJing,

Wang ChenChao,

Zhu Shuai,

Dai ChunYang,

Wu YanChao

Publication year - 2015

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400898

Subject(s) - annulation , chemistry , ruthenium , catalysis , triphenylphosphine , transfer hydrogenation , hydrogen , cascade , photochemistry , medicinal chemistry , organic chemistry , combinatorial chemistry , chromatography

The synthesis of quinolines from alcohols and 2‐nitrobenzaldehydes is described. Unreactive alcohols and 2‐nitrobenzaldehydes were concurrently converted to the reactive reactants for a Friedländer annulation via a hydrogen transfer. Tris(triphenylphosphine)ruthenium(II) dichloride [Ru(PPh 3 ) 3 Cl 2 ] appeared to serve the dual role of an efficient hydrogen transfer catalyst and a suitable Friedländer annulation catalyst.

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