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Copper‐Catalyzed Direct Arylselenation of Anilines by CH Bond Cleavage
Author(s) -
Ricordi Vanessa G.,
Thurow Samuel,
Penteado Filipe,
Schumacher Ricardo F.,
Perin Gelson,
Lenardão Eder J.,
Alves Diego
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400804
Subject(s) - chemistry , copper , aryl , catalysis , bond cleavage , regioselectivity , cleavage (geology) , iodide , sulfoxide , medicinal chemistry , polymer chemistry , organic chemistry , combinatorial chemistry , alkyl , geotechnical engineering , fracture (geology) , engineering
We describe here an efficient and regioselective synthesis of arylselanyl anilines by copper‐catalyzed direct arylselenation of arylamines. Using a catalytic amount of copper iodide in dimethyl sulfoxide at 110 °C under an air atmosphere, a range of arylselanyl anilines was obtained directly from substituted diaryl diselenides in moderate to good yields via CH bond cleavage of aryl amines.
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