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Rhodium(III)‐Catalyzed ortho ‐Arylation of Anilides with Aryl Halides
Author(s) -
Haridharan Radhakrishnan,
Muralirajan Krishnamoorthy,
Cheng ChienHong
Publication year - 2015
Publication title -
advanced synthesis and catalysis
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.541
H-Index - 155
eISSN - 1615-4169
pISSN - 1615-4150
DOI - 10.1002/adsc.201400798
Subject(s) - rhodium , chemistry , phenanthridine , aryl , halide , catalysis , derivative (finance) , medicinal chemistry , combinatorial chemistry , organic chemistry , alkyl , financial economics , economics
An efficient o‐ arylation of pivalamides by aryl iodides via rhodium(III)‐catalyzed C–H activation is demonstrated for the first time. Further, the biaryl products can be converted effectively into biologically active phenanthridine and phenanthridinone derivative.