N‐Heterocyclic Carbene‐Catalyzed Benzoin Strategy for Divergent Synthesis of Cyclitol Derivatives from Alditols | Zendy

Kang Bubwoong | Zendy; Sutou Toshiaki | Zendy; Wang Yinli | Zendy; Kuwano Satoru | Zendy; Yamaoka Yousuke | Zendy; Takasu Kiyosei | Zendy; Yamada Kenichi | Zendy

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N‐Heterocyclic Carbene‐Catalyzed Benzoin Strategy for Divergent Synthesis of Cyclitol Derivatives from Alditols

Author(s) -

Kang Bubwoong,

Sutou Toshiaki,

Wang Yinli,

Kuwano Satoru,

Yamaoka Yousuke,

Takasu Kiyosei,

Yamada Kenichi

Publication year - 2015

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400712

Subject(s) - cyclitol , chemistry , benzoin , carbene , catalysis , organic chemistry , stereochemistry , biochemistry , receptor , inositol

A divergent synthesis of cyclitol derivatives has been developed utilizing an N‐heterocyclic carbene‐catalyzed benzoin‐type cyclization of C 2 ‐symmetrical dialdoses. The resulting inososes are versatile intermediates, which are readily converted into not only inositols but also amino‐, deoxy‐, O ‐methyl‐ and C ‐methyl‐inositols.

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