Studies on Palladium‐Catalyzed Synthesis of Dihydrocycloocta‐ [ b ]indoles and their Thermal Reactivities with Maleimide or Maleic Anhydride | Zendy

Zhu Can | Zendy; Ma Shengming | Zendy

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Studies on Palladium‐Catalyzed Synthesis of Dihydrocycloocta‐ [ b ]indoles and their Thermal Reactivities with Maleimide or Maleic Anhydride

Author(s) -

Zhu Can,

Ma Shengming

Publication year - 2014

Publication title -

advanced synthesis and catalysis

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.541

H-Index - 155

eISSN - 1615-4169

pISSN - 1615-4150

DOI - 10.1002/adsc.201400644

Subject(s) - maleimide , chemistry , maleic anhydride , palladium , catalysis , cycloaddition , organic chemistry , carbon fibers , hydrogen , polymer chemistry , medicinal chemistry , polymer , copolymer , materials science , composite number , composite material

A palladium(0)‐catalyzed reaction of 2‐allyl‐3‐indolyl boronates/propargylic carbonates was observed to afford dihydrocycloocta[ b ]indoles highly efficiently via carbon‐carbon coupling, [1,5]‐hydrogen migration involving dearomatization, and electrocyclization involving rearomatization. Their thermal reactions with the addition of dienophiles involving eletrocyclization and [4+2] cycloaddition have been studied.

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